Friction-wear Properties and Mechanism of Hard Facing Pairs of SiC and WC

YAO Xiu-Min, WANG Xiao-Jie, LIU Xue-Jian, CHEN Zhong-Ming, HUANG Zheng-Ren



Friction-wear Properties and Mechanism of Hard Facing Pairs of SiC and WC

YAO Xiu-Min, WANG Xiao-Jie, LIU Xue-Jian, CHEN Zhong-Ming, HUANG Zheng-Ren

(The State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China)

Sliding friction-wear properties of pressurelessly solid-state-sintered silicon carbide ceramics (SSiC) and liquid-phase-sintered SiC ceramics (LPSiC) pairing with tungsten carbide (WC) were researched under the frictions with or without lubrication. Under dry friction, as compared to LPSiC/WC pairs, SSiC/WC pairs have higher friction coefficient () and less mass loss (Δ) due to SSiC ceramics have larger particle size and higher hardness. The surface topography of worn area was detected by SEM companying with elements mapping and micro-area XRD technology. The micro plough cut and micro fracture led to the wear of SiC ceramics. Its fatigue damage led to the wear of WC materials. The grinding-out WC grains were oxidized to amorphous WO3phase due to the friction heat generated in the friction. Under the wet friction with water as lubrication, as compared to SSiC/WC pairs, LPSiC/WC pairs have higher friction coefficient and less mass losses. Whether under dry friction or wet friction, the pairs with SiC ceramics as the fixed materials have lowerand Δthan those with SiC ceramics as the rotated materials.

hard facing; sliding wear; friction pairs; surface topography; wear modeling

Silicon carbide (SiC) has been used as abrasive and seal materials, due to its unique properties, such as low density, high strength, high thermal conductivity, high hardness, high elastic modulus, excellent thermal shock resistance and superior chemical inertness. In order to ensure the safety of the engineering use, the friction- wear properties of SiC ceramics must be investigated. Microstructure engineering has been proved to be an effective strategy to improve the silding-wear resistance of polycrystalline structure ceramics[1-4].

In recent years, pressurelessly sintered silicon carbide (PLS SiC) ceramics developed as a new kind of seal materials due to its high strength, good oxidation resistance and excellent chemical resistance. It can be submerged in the corrosive environments, subjected to extreme wear and abrasive conditions, and exposed to the temperatures exceeding 1400 ℃. There are two kinds of PLS SiC ceramics, one is solid-state-sintered SiC ceramics (SSiC), which are usually prepared by adding B-C as sintering aids, the other is liquid-phase-sintered SiC ceramics (LPSiC), which are usually fabricated by adding Al2O3-Y2O3as sintering aids[5-6]. The different composition and microstructure endow them with different properties including the friction properties.

Sang,[7]researched the friction properties of reaction-sintered Si/SiC paring with Si/SiC-Ni materials or themselves in the temperature range of 15-600 ℃. The results showed that the friction properties of the Si/SiC could be improved by addition of Ni. Sasaki,[8]indicated the surrounding atmosphere affected the friction and wear of LPSiC ceramics, such as humid air or water, the results revealed that the wear rate of SiC decreased with increase in relative humidity. Lopez,[9-11]found that the friction properties of LPSiC ceramics paring with Si3N4ball were influenced by the SiC particle size, the content of intergranular phase, the internal tensile residual stress and hardness. Cho,[12]researched the wear and wear transition of HP SiC and HPLP SiC-TiB2ceramics paring with SiC ball, the results showed that the wear behavior of them were influenced by the grain boundary strength. Llorente,[13]resea­rched the dry tribological performance of graphene/ silicon carbide composites paring with silicon nitride balls. The result showed that, compared with monolithic SiC, the graphene nanoplatelets (GNPs) can improve wear resistance because it can form an adhered lubri­cating and protecting tribofilm in the wear process. Lafon-Placette,[14]researched tribological properties of SiC/SiC and SiC/C pairs using a ring-on-ring device under dry friction, the wear mechanisms were found to be driven by cracking process and oxidation.

In recent years, in some harsh operation conditions, especially high rotation speed and high temperature system, the mechanical seal tends to be hard-face to hard-face seal due to their excellent wear resistance and long service life, such as, SiC/WC pairs. Until now, there are few research reports on the sealing properties and friction properties of those pairs.

In this work, we focused on the friction-wear properties of SiC/WC pairs. The properties and microstructure of the materials were analyzed. The friction-wear properties, friction surface and friction mechanism of them were also discussed.

1 Experimental procedure

1.1 Samples preparations

SSiC ceramics were prepared with 96.4wt%-SiC powders (50=0.5mm, SIKA TECH., Lillesand, Norway), 3.0wt% carbon black and 0.6wt% boron carbide particles as raw materials. The raw materials were ball milled with ethanol as media, dried at 60 ℃. After being meshed, the powders were died pressed at 40 MPa, cold isostaticly pressed at 200 MPa to fabricate green samples, then the as-prepared specimens were sintered at 2150 ℃ for 1 h to obtain the ceramics.

LPSiC ceramics were prepared with 93wt%-SiC powders, 3.12wt% Al2O3pwders (Fenghe Ceramic Co., Ltd., China) and 3.88wt% Y2O3powders (Yuelong Chemical Co., Ltd., China) as raw materials. The procedure to fabricate LPSiC ceramics was the same with that of SSiC ceramics except that they were finally sintered at 1930 ℃ for 1 h.

The WC materials (N200, 8wt%~9wt% Ni-0.8~1.2wt% (Cr+Mo)-89.8wt%~91.2wt% WC) were provided by KLT Carbide Co. Ltd., Sichuan, China, which were fabricated by gas pressure sintering method.

The as-sintered samples were machined into rectangular blocks with a dimension of 6 mm×7 mm×30 mm and rings with a dimension of internal diameter16 mm and external diameter40 mm. And the thickness of the rings was 10 mm. The surfaces of the bars were polished using polishing machinery with diamond slurries.

1.2 Test and characterization

The bulk densities of the samples were measured by Archimedes method using distilled water as immersing medium. The Vickers’ hardness (v) of the samples was measured on the polished surfaces by Vickers indentation (Wilson-Wolpert Tukon 2100B, Canton, MA) using a load of 3 kg. Rockwell hardness (HRA) of the samples was tested on the polished surfaces by Rockwell indentation (Wilson-2000, Canton, MA) using a load of 60 kg. Fracture toughness (IC) of the samples was calculated by the Vickers indentation method on the basis of the equation proposed by Niihara,[15]. The worn areas and the chemical composition of the samples were investigated by scanning electron microscope (SEM, JXA-8100, JEOL, Japan) with an energy dispersive spectrometer. The debris phases on the surface of the friction surface were determined by micro-area XRD technology (Bruker D8 DISCOVER X-Ray, Bruker Corp., Germany).

The friction test was performed on a ring-block friction testing machine (MM200, Jinan test machine factory, China). During the friction, the ring was rotated and the block was fixed. In the present study, four groups of samples were tested without lubrication (dry friction) or with water as lubrication in every pairs (WC/SSiC,WC/LPSiC,SSiC/WC,LPSiC/WC). The rotation speed and load were 400 r/min (0.82 m/s) and 196 N, respectively. Three pairs of samples were tested in every friction condition. The specimens were cleaned before and after the tests by immersing in acetone with agitation in an ultrasonic bath for 20 min to calculate the weight loss during the friction process.

2 Results and discussion

Table 1 shows the properties of the used materials. It can be clearly seen that the relative density of these three kinds of materials are over 99%, which means that the samples are highly densified and have few visible pores (seen in Fig. 1). By comparison, the SSiC ceramics have the lowest fracture toughness and highest hardness, the WC materials have the highest fracture toughness and lowest hardness, and the fracture toughness and hardness of LPSiC ceamics are in the median.

Table 1 Properties of the prepared materials

Fig. 1 Fracture microstructures of three kinds of samples

(a) SSiC materials; (b) LPSiC materials; (c) WC materials

Figure 1 shows the fracture surface microstructures of these three kinds of samples. It can be seen that the fracture mode of SSiC cermics is complete transgranular fracture, showing the strong interface bonding between the SiC grains. Compared with the other two kinds of materials, SSiC ceramics were obtained at higher temperaturea solid-state sintering route, so SSiC ceramics had bigger grain sizes of about 3-5 μm. Both of them led to the higher hardness and lower fracture toughness of SSiC ceramics. It can be also seen that the fracture mode of LPSiC ceramics is mainly intergranular fracture because of the interface YAG phases between SiC grains, which were formed during the liquid-phase-sintering process and led to the weak interface bonding between the SiC grains. And the SiC particle sizes in LPSiC ceramics are about 1-2 μm due to their lower sintering temperature. Interface phase, intergranular fracture mode and smaller particle sizes led to the lower hardness and higher fracture toughness of LPSiC ceramics. In the WC samples, the grain sizes of WC particles are smaller than 3 μm, the highest fracture toughness and lowest hardness of the samples were obtained due to their metal features.

Table 2 and 3 show the friction properties of different SiC/WC pairs. Under dry friction condition, all friction pairs have higher friction coefficient (). However, compared with the pairs containing SSiC ceramics, the pairs containing LPSiC ceramics have lower friction coefficient and higher friction mass loss. It is well documented that coarser ceramics have poorer sliding- wear property[16-17], in which the wear-mechanism transition occurs sooner from initial mild wear controlled by dislocation plasticity to severe fracture-controlled wear[12]. The SiC grain sizes in the SSiC ceramics are bigger than those in the LPSiC ceramics, which leads to the quicker friction mechanism transition from mild wear to severe fracture-controlled wear, which is in consistent with Sang’s results[7]on SiC-Si ceramics. At the same time, the stronger grain bonding between SiC grains in the SSiC ceramics leads the fracture occurred inside the grains, both of which lead to the higherof those containing SSiC pairs. From Table 1, the hardness of LPSiC ceramics is lower than that of SSiC ceramics, and the former contains a large amount of YAG phases, which have lower hardness (~15 GPa)[18]. Both of them led to higher mass losses of LPSiC ceramics in the friction.

From Table 3, it can be seen that, with water as lubrication, theof all pairs are lower than 0.1 and the mass loss can be negligible. Meanwhile, theof LPSiC/WC pairs is higher than that of SSiC/WC pairs, which is contrary to that of dry friction.

Table 2 Friction properties of different pairs of SiC/WC under dry friction

Table 3 Friction properties of different pairs of SiC/WC with water as lubrication

From Table 2 and 3, in SiC/WC pairs, when SiC ceramics (both SSiC and LPSiC ceramics) were as fixed friction materials (as blocks), theof the pairs is lower than that with WC materials as fixed friction materials. Under fry friction, the wear rate of the former is higher than that of the latter. Therefore, in order to decrease, it is a good option to choose the SiC ceramics as the fixed friction materials; in order to decrease the wear, it would be better to choose WC materials as the fixed friction materials in the SiC/WC friction pairs.

Figure 2 shows the wear face microstructure of the blocks in different WC/SiC pairs under dry friction. Comparing with SiC ceramics as the fixed blocks, the friction marks of WC materials as the fixed blocks are fewer, and there are no obvious SiC materials on the surfaces of WC blocks (seen in Fig. 2(a) and (b)). However, there is a lot of debris on the surface of SiC ceramics (seen in Fig. 2(c) and (d)). Both of them show that the wear rate of the pairs with SiC as the fixed friction materials is higher than that of the pairs with WC as the fixed friction materials, which is in agreement with the result in Table 2. It can be also seen that no WC particles are pulled out on the surface of WC materials. Because the friction test is ring-to-block mode, the friction heat was mainly produced in the friction surface and stored in the block, which led to the severe wear of the block. When WC materials were used as blocks, plastic deformation took place continuously in the WC materials due to its high toughness. In the end, cracks were induced by fatigue damage (seen in Fig. 2(b)) and the roughness of WC materials increased, which led to the increase of friction coefficient. With SiC materials as the fixed blocks, a lot of debris were observed on the over worn surfaces, which demonstrated that SiC ceramics or WC materials were worn down.

Fig. 2 Wear face microstructures of the blocks in different WC/SiC pairs without lubrication

(a)SSiC/WC; (b)LPSiC/WC; (c)WC/SSiC; (d)WC/LPSiC

Figure 3 shows the worn face microstructure of SiC samples in different pairs. From Fig. 3(a), cracks are detected in SSiC ceramics after dry friction test, while no cracks are found in the LPSiC ceramics in the detected area. Usually for the same materials, the tendency of crack’s formation is stronger in the samples of fine particles than that of coarse ones, because the peak stress could be limited due to a uniform distribution of the stress for the coarse particles[19]. In the experiments, LPSiC ceramics have higher fracture toughness, which leads them have good resistance to crack propagation. Therefore, no cracks are observed in the worn face of LPSiC ceramics. After being rubbed with WC, the obvious scratches are observed on the worn surface of SSiC blocks along the friction direction, and large amounts of debris (the white parts in Fig. 3) were produced. At the same time, almost all SiC particles are broken in the worn area of SSiC ceramics (shown by the inset figure in Fig. 3(a)). It can be concluded that the micro plough cut and micro fracture existed in the friction process of SSiC ceramics. From Fig. 3(b), it can be seen that there is more debris on the surface of LPSiC samples than that on the surface of SSiC samples, which is in agreement with the data in Table 2. No obvious scratches and grain fracture were observed on the surface of LPSiC samples due to the large amount of debris. However, from the magnified macrostructure in the Fig. 3(b), the grain pullout is detected, which is attributed to the weak interface bonds in LPSiC ceramics, and the particle sizes of the most debris are nanometers. From Fig. 3(c) and (d), with water as lubrication, there are slight scratch marks and a few debris on the worn faces of SiC ceramics, which means SiC ceramics have good lubrication performance.

Fig. 3 Wear face microstructures of SiC samples in different pairs

(a)WC/SSiC under dry friction; (b)WC/LPSiC under dry friction; (c)WC/SSiC with water as lubrication; (d)WC /LPSiC with water as lubrication

Figure 4 shows the EDS mapping of the worn surface of SSiC blocks inWC/SSiC pairs. Obviously, the Si element matches with C element very well in these areas. It can be also seen that W element matches quite well with O element, which indicated that WO3was formed in the wear area. The existence of WO3indicated that oxidative wear occurred in the dry friction. The same phenomena were observed in theWC/LPSiC samples. During the friction process, the SiC particles were broken in SSiC samples and pulled out in LPSiC ceramics under the applied force, which were as the abrasive to wear the samples and produce the debris. From Fig. 3(b), the sizes of WO3particles were lower than 200 nm. Smaller debris size and a large amount of friction heat led to the oxidation of WC debris into WO3. And the soft WO3phase is beneficial to reduce the friction efficient.

Figure 5 shows the micro-area XRD pattern of the worn surface of SSiC blocks inWC/SSiC pairs under dry condition. The result showed that the debris consists of SiC as a major phase and graphite as the co-existence phase. No WC, WO3and SiO2phases are detected. Both of them indicated that all abrasive WC phases were transferred to WO3(seen in Fig. 4), which existed as an amorphous phase. At the same time, the peaks of SiC phase were similar to the original SSiC ceramics, which meant few SiC phase existed in the debris. Therefore, the X-ray diffraction pattern of SiC phases were from the original SSiC ceramics. The same phenomenon was observed inWC/LPSiC pairs.

3 Conclusions

Friction-wear properties of different SiC/WC pairs were investigated under dry friction conditions or with water as lubrication. Compared to LPSiC/WC pairs, the SSiC/WC pairs have higher friction coefficient and less mass loss because SSiC ceramics have larger particles size and higher hardness. The friction coefficient of the pairs with SiC ceramics as the fixed friction materials is lower than that with WC materials as the fixed friction materials. The wear rate of the former is higher than that of the latter due to the lower hardness of WC. The WC debris was oxidized to amorphous WO3phase due to friction heat and the smaller debris sizes.

Fig. 4 EDS mapping of the worn surface of SSiC blocks in ΦWC/SSiC pairs

Fig. 5 Micro-area XRD pattern of the worn surface of SSiC blocks in ΦWC/SSiC pairs under dry friction

[1] BORRERO-LÓPEZ O, ORTIZ AL, GUIBERTEAU F,. Effect of microstructure on sliding-wear properties of liquid-phase-sintered-SiC., 2005, 88(8): 2159–2163.

[2] BORRERO-LÓPEZ O, ORTIZ AL, GUIBERTEAU F,. Sliding- wear resistant liquid-phase sintered SiC processed using-SiC starting powders., 2007, 90(2): 541–545.

[3] BORRERO-LÓPEZ O, ORTIZ AL, GUIBERTEAU F,. Microstructural design of sliding-wear-resistant liquid-phase-sintered SiC: an overview., 2007, 27(11): 3351–3357.

[4] BORRERO-LÓPEZ O, ORTIZ AL, GUIBERTEAU F,. Effect of the nature of the intergranular phase on sliding-wear resistance of liquid-phase-sintered-SiC., 2007, 57(6): 505–508.

[5] ALLIEGRO R, COFFIN L, TINKLEPAUGH J. Pressure-sintered silicon carbide., 1956, 39(11): 386–389.

[6] OMORI M, TAKEI H. Pressureless sintering of SiC., 1982, 65(6): c92–c92.

[7] SANG K Z, JIN Z H. Unlubricated friction of reaction-sintered silicon carbide and its composite with nickel., 2000, 246(1/2): 34–39.

[8] SASAKI S. The effect of the surrounding atmosphere on the friction and wear of alumina, zirconia, silicon carbide and silicon nitride., 1989, 134(1): 185–200.

[9] BORRERO-LÓPEZA O, ORTIZA AL, GUIBERTEAUA F,. Effect of liquid-phase content on the contact-mechanical properties of liquid-phase-sintered-SiC., 2007, 27(6): 2521–2527.

[10] BORRERO-LÓPEZA O, ORTIZA AL, GUIBERTEAUA F. Improved sliding-wear resistance-toughened silicon carbide., 2005, 88(12): 3531–3534.

[11] CIUDAD E, BORRERO-LÓPEZ O, RODRÍGUEZ-ROJAS F,. Effect of intergranular phase chemistry on the sliding-wear resistance of pressureless liquid-phase-sintered-SiC., 2012, 32(2): 511–516.

[12] CHO S J, UM C D, KIM S S. Wear and wear transition in silicon carbide ceramics during sliding., 1996, 79(5): 1247–1251.

[13] LLORENTE J, ROMAN-MANSO B, MIRANZO P,. Tribological performance under dry sliding conditions of graphene/silicon carbide composites., 2016, 36(3): 429–435.

[14] LAFON-PLACETTE S, DELBE K, DENAPE J,. Tribological characterization of silicon carbide and carbon materials., 2015, 35(4): 1147–1159.

[15] NIIHARA K, MORENA R, HASSELMAN D. Evaluation ofICof brittle solids by the indentation method with low crack-to-indent ratios., 1982, 1(1): 13–16.

[16] CHO S J, HOCKEY B J, LAWN B R,. Grain-size and R-curve effects in the abrasive wear of alumina., 1989,72(7): 1249–1252.

[17] CHO S J, UM C D, KIM S S. Wear and wear transition mechanism in silicon carbide during sliding., 1995, 78(4): 1076–1078.

[18] DEWITH G, PARREN J. Translucent Y3Al5O12ceramics-mechanical- properties., 1985, 16(1–4): 87-93.

[19] SANG K Z, LIU L, JIN Z H. Improvements on dry friction and wear properties for reaction-sintered silicon carbide by the matching size of SiC particles., 2007, 28(2): 735–738.

碳化硅/碳化钨硬面密封摩擦副的摩擦磨损性能和机理研究

姚秀敏, 王晓洁, 刘学建, 陈忠明, 黄政仁

(中国科学院 上海硅酸盐研究所, 高性能陶瓷和超微结构国家重点实验室, 上海 201899)

实验研究了干摩擦和水润滑条件下, 常压固相烧结碳化硅陶瓷(SSiC)及常压液相烧结碳化硅陶瓷(LPSiC)分别与碳化钨(WC)组成的硬面配对摩擦副的滑动摩擦磨损性能。在干摩擦条件下, 与LPSiC/WC摩擦副相比, SSiC陶瓷由于具有更大的晶粒尺寸和硬度, 导致SSiC/WC摩擦副具有更大的摩擦系数和更小的磨损量。磨损区域的SEM形貌结合面扫描分析、微区XRD分析结果表明: 微犁沟和微断裂导致SiC陶瓷的磨损, 疲劳损伤导致WC材料的磨损, 而摩擦过程产生的摩擦热导致磨出的WC颗粒氧化成无定型WO3。在水润滑条件下, 与SSiC/WC摩擦副相比, LPSiC/WC摩擦副具有更大的摩擦系数和更低的磨损率。在干摩擦和水润滑条件下, 与SiC陶瓷作为动摩擦副配对相比, SiC陶瓷作为固定摩擦副的摩擦配对具有更小的摩擦系数和质量损失。

硬面密封; 滑动摩擦; 摩擦副; 表面形貌; 磨损机制

TQ174

A

2018-09-14;

2018-12-18

Natural Science Foundation of Shanghai (17ZR1434500)

YAO Xiu-Min (1973-), female, PhD. E-mail: xmyao@mail.sic.ac.cn

HUANG Zheng-Ren, professor. E-mail: zhrhuang@mail.sic.ac.cn

1000-324X(2019)06-0673-06

10.15541/jim20180435