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附件D:单相合金系的平衡全息网络相图

2015-11-19

中国有色金属学报 2015年10期
关键词:单相全息热力学

附件D:单相合金系的平衡全息网络相图

以Au3Cu型亚格子系统为例,介绍了全套热力学性质qe-T-x平衡三维网络相图(见图D.1)[8]。

(To be continued)

(To be continued)

图D.1 Au3Cu-型亚格子系统的q-x-T平衡全息网络相图Fig.D.1 EHNP diagrams of q-x-T of Au3Cu-type sublattice system:(a)Mixed Gibbs energy ΔGm-x-T three-dimension EHNP diagram;(b)Mixed characteristic Gibbs energy-x-T three-dimension EHNP diagram, without including configuration entropy;(c)Mixed enthalpy ΔHm-x-T three-dimension EHNP diagram;(d)Mixed potential energy ΔEm-x -T three-dimension EHNP diagram, without including variations in AG-potential energies with temperatures;(e)Mixed volume ΔVm-x-T three-dimension EHNP diagram;(f)Generalized mixed vibration free energy ΔXv-x-T three-dimension EHNP diagram;(g)Generalized mixed vibration energy ΔUv-x-T three-dimension EHNP diagram, including variations in AG-potential energies with temperatures;(h)Generalized mixed vibration entropy ΔSv-x-T three-dimension EHNP diagram;(i)Heat capacity-x-T three-dimension EHNP diagram;(j)Thermal expansion coefficient α-x-T three-dimension EHNP diagram;(k)Activity aAu-x-T three- dimension diagram;(l)Activity aCu-x-T three-dimension diagram

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