“生物质高质化利用过程中节能与CO2利用和减排”年度报告

肖睿

摘要：研究生物质高质化利用过程中节能与CO2利用和减排理论和技术，按照任务书的要求，采用生物油在低温（<125 °C）、高效稳定催化剂（Ru/C）作用下进行选择性加氢，制备易于分离的气态烯烃和液态芳香烃类化合物等化学品。开展了二种生物质低温气化制SNG的研究，另外针对常规的测试技术，进一步认识了气固流化床特别是稠密气固流化床复杂的流体动力学特性，攻克了微波加热-红外热成像技术用于颗粒示踪研究的一系列技术难题。开展了以苯为模化物的生物质焦油催化气化实验研究。通过本年度的研究在生物质低温气化制SNG的研究过程中获得了合适的催化剂，研究了温度和压力对产物的影响。在此基础上，发展了“微波加热—红外热成像”颗粒示踪测量新方法，解决了常规测试技术难以获得三位尺度上的颗粒运动信息难题，并成功应用于喷动流化床内颗粒示踪的研究，获得了异重颗粒在床内的颗粒循环模式、循环周期分布和停留时间分布。另外在催化分解脱除气化产物中焦油的研究过程中，得到了温度、水蒸汽量、床高和床料等因素对脱除焦油模化物的影响规律。

关键词：生物质；热解；二氧化碳利用与减排

Abstract：The research studied the theory and technology of energy-saving， CO2 application and emission-reduction during biomass high-efficient utilization. In accordance with the requirements of the mission statement， bio-oil was selective hydrogenated under low temperature （<125 ℃） with high-efficient and stable catalyst （Ru/C） to generate easily separated gaseous olefins and aromatic hydrocarbons in liquid form. Biomass low-temperature gasification was also carried out to generate syngas. Besides， the complex fluid dynamics of fluidized bed， especially dense fluidized bed， was further understood. A series of technical problems for applying of microwave heating-IR thermal imaging technology for particle tracing was conquered. Benzene was used as model compound for experimental study of biomass tar catalytic gasification. The research in this year found a suitable catalysis for low-temperature biomass gasification to syngas， the effects of temperature and pressure on the product distribution was also revealed. Based on these， “microwave heating-infrared thermography” particles tracing method was developed to solve the three-dimensional particle motion information problem which is difficult to obtain by conventional testing methods. This new method has successfully applied to spouted fluidized bed， revealing the particle circulating mode， cycle distribution and residence time distribution of the heavy particles. Whats more， during the study of gasification tar removal by catalytic decomposition process， the influence of temperature， water vapor， bed height and bed material on the process was also analyzed. Significant research results are as follows： bio-oil catalytic conversion to chemicals will jointly published an article on SCIENCE in the near future. The achievement of flow reactor coupled with the reaction has received the second award for 2010 National Science and Technology Progress， 12 papers were also published， with an invention patent. CO2 high-efficient absorption with the biomass production published 1 SCI papers and applied 2 invention patents. Biomass by-product catalytic carbonization to produce high performance electromagnetic shielding materials published 1 SCI， 1 EI and 1 core journal papers， and obtained 2 invention patents， 2 new utility patents， and applied 1 invention patent. The use of separated CO2 to synthesis carbonate materials has published 2 SCI papers， and applied 1 invention patent.

Keywords：Biomass； Pyrolysis； CO2 utilization and emission reduction

閱读全文链接（需实名注册）：http：//www.nstrs.cn/xiangxiBG.aspx？id=48934&flag=1